| 1901 | COMPAÑIA DE TRANSPORTE ESCOLAR E INSTITUCIONAL TRANSLIBERTADOR S.A. | US$ 4.224.097 | US$ 117.455 | 8 | Pichincha |
| 1902 | BALANCEADOS ISABELA S.A.S. | US$ 3.930.221 | US$ 42.158 | 6 | Tungurahua |
| 1903 | LEXVALOR ASESORIA LEGAL S.A. | US$ 4.777.470 | US$ 17.414 | 72 | Pichincha |
| 1904 | CONSTRUCTORES Y DESARROLLADORES ACUÍCOLAS CONDESACU S.A.S. | US$ 2.333.808 | US$ 9.957 | 21 | Guayas |
| 1905 | CAFE GARDELLA S.A. | US$ 4.055.651 | US$ 41.692 | 16 | Guayas |
| 1906 | TERMOEK TERMOENCOGIBLES Y EMPAQUES S.A. | US$ 3.719.451 | US$ 90.907 | 56 | Guayas |
| 1907 | NEWCASTLECORP S.A. | US$ 2.316.929 | US$ 2.195.501 | 1 | Guayas |
| 1908 | COMPAÑIA DE AUTOMATIZACION INDUSTRIAL EUROINSTRUMENTS INGENIERIA CIA. LTDA. | US$ 4.837.823 | US$ 516.632 | 22 | Pichincha |
| 1909 | AGROLUA S.A. | US$ 1.159.696 | US$ 87.507 | 21 | Santo Domingo De Los Tsachilas |
| 1910 | BOONKER S.A. | US$ 2.672.066 | US$ 49.680 | 34 | Pichincha |
| 1911 | GUSBER S.A. | US$ 3.340.120 | US$ 376.246 | 26 | Guayas |
| 1912 | DON PECHE S.A. AGROPECHE | US$ 4.326.940 | US$ 79.963 | 93 | Guayas |
| 1913 | CLIMAPOWER S.A. IMPORTADORA Y COMERCIALIZADORA | US$ 3.974.830 | US$ 291.629 | 48 | Pichincha |
| 1914 | INSUMOS AGRICOLAS NUEVOAGRO CIA. LTDA. | US$ 3.295.435 | US$ 75.035 | 28 | Pichincha |
| 1915 | MIAVE S.A.S. | US$ 4.011.942 | US$ 241.406 | 37 | Cotopaxi |
| 1916 | DISMOTEXTIL S.A. | US$ 2.789.709 | US$ -211.626 | 83 | Pichincha |
| 1917 | SAMIR TECHNOLOGY S.A. SAMIRTECH | US$ 3.095.863 | US$ 51.475 | 4 | Guayas |
| 1918 | CALGUAYAS S.A. | US$ 1.750.628 | US$ 38.585 | 11 | Guayas |
| 1919 | TIERRAVID S.A.S. | US$ 3.208.566 | US$ 239.432 | 24 | Guayas |
| 1920 | NEGOCIOS INTEGRADOS VANEGI CIA. LTDA. | US$ 4.759.099 | US$ 17.259 | 9 | Pichincha |
| 1921 | SEGPROSER CIA. LTDA. | US$ 3.392.782 | US$ 1.308 | 412 | Azuay |
| 1922 | COMPAÑIA GUERRERO CONSTRUCCIONES S.A. GUECONSTRUSA | US$ 3.931.558 | US$ 107.109 | 283 | Guayas |
| 1923 | CARD PROCESSING TECNOLOGY CAPTEC S.A. | US$ 3.146.120 | US$ 145.827 | 31 | Pichincha |
| 1924 | EMPRESAS CAROZZI ECUADOR S.A. | US$ 3.324.467 | US$ -42.129 | 14 | Guayas |
| 1925 | IMPORTACIONES MÉDICAS DIRECTAS IMEDI S.A.S. | US$ 2.113.653 | US$ 121.455 | 3 | Manabi |
| 1926 | EQUAFRESH MORA CASTILLO EQMC CIA.LTDA. | US$ 1.849.524 | US$ -2.302 | 106 | El Oro |
| 1927 | AIRMAXTELECOM SOLUCIONES TECNOLOGICAS S.A. | US$ 3.769.599 | US$ 73.540 | 97 | Imbabura |
| 1928 | ENROBAN S.A.S. | US$ 3.084.504 | US$ 56.216 | 61 | Guayas |
| 1929 | INDOMABLE S.A.S. | US$ 1.897.798 | US$ 1.786.891 | 1 | Pichincha |
| 1930 | COMERCIAL TEODORO LARRIVA CIA. LTDA. | US$ 3.807.994 | US$ -491.188 | 29 | Azuay |
| 1931 | ECUATORIANA DE LENTES ELENS S.A. | US$ 3.214.169 | US$ 7.056 | 50 | Pichincha |
| 1932 | HOLDING MA-AMCC S.A.S. | US$ 1.063.936 | US$ 1.246.927 | 2 | Pichincha |
| 1933 | GAYATA S.A. | US$ 2.821.095 | US$ 48.499 | 8 | Guayas |
| 1934 | NM & ASOCIADOS S.A. | US$ 1.596.589 | US$ 15.947 | 8 | El Oro |
| 1935 | GUALAQUIZA INGENIEROS S.A. | US$ 2.085.648 | US$ 232.002 | 45 | El Oro |
| 1936 | FLORES DE TUMBABIRO S.A. FLORETUM | US$ 3.750.558 | US$ 59.494 | 126 | Imbabura |
| 1937 | ALEXA TEJIDOS CIA. LTDA. | US$ 2.542.677 | US$ -91.223 | 81 | Pichincha |
| 1938 | HAMBURG SÜD ECUADOR S.A. | US$ 3.725.251 | US$ -28.885 | 41 | Guayas |
| 1939 | PLANIFIKT S.A. | US$ 1.791.547 | US$ 22.074 | 162 | Guayas |
| 1940 | LANGOSTINO S.A. (LANCONOR) | US$ 2.469.312 | US$ -204.933 | 2 | Guayas |
| 1941 | PLASTICOS PARA BANANO BANAPLAST S.A. | US$ 2.491.960 | US$ 4.646 | 35 | El Oro |
| 1942 | EBTEL CIA. LTDA. | US$ 4.632.513 | US$ 26.338 | 20 | Pichincha |
| 1943 | KOLVECH S.A. | US$ 4.344.280 | US$ 215.948 | 27 | Guayas |
| 1944 | YOUXIN CIA.LTDA. | US$ 4.107.370 | US$ 58.133 | 39 | El Oro |
| 1945 | PALHARMONY FLAVOURS & INGREDIENTS S.A. | US$ 2.879.779 | US$ 20.886 | 12 | Guayas |
| 1946 | CAMARTAU S.A. | US$ 2.100.456 | US$ 28.366 | 15 | Guayas |
| 1947 | COMERCIAL MAYA CIA.LTDA. | US$ 3.579.069 | US$ -403.494 | 22 | Tungurahua |
| 1948 | BRITRANSFORMADORES S.A. | US$ 3.304.249 | US$ 117.756 | 46 | Guayas |
| 1949 | BFS ECUADOR S.A. | US$ 4.506.721 | US$ 17.735 | 59 | Pichincha |
| 1950 | PELICANOS Y PIQUEROS ENJOYMENT S.A. | US$ 2.001.995 | US$ 1.211 | 4 | Pichincha |
| 1951 | VAZCLOTHES S.A.S. | US$ 3.883.569 | US$ 80.159 | 84 | Tungurahua |
| 1952 | BALANCEADOS DEL MAR MARAQUATIC S.A. | US$ 3.720.840 | US$ 40.581 | 8 | Guayas |
| 1953 | GASOP COMPANY S.A. | US$ 4.609.749 | US$ 69.352 | 14 | Guayas |
| 1954 | HONEYWELL PERU S.A. | US$ 3.342.198 | US$ 172.957 | 4 | Pichincha |
| 1955 | ESACONTROL SA | US$ 2.689.730 | US$ 390.867 | 36 | Pichincha |
| 1956 | COMERCIALIZADORA BIOCOMBUS S.A. | US$ 4.249.453 | US$ 15.060 | 4 | Pichincha |
| 1957 | ECUATRONIX CIA LTDA | US$ 1.667.276 | US$ -3.254 | 85 | Pichincha |
| 1958 | MANTAHOSPITALCENTER MHC S.A.S. | US$ 1.790.161 | US$ -97.960 | 12 | Manabi |
| 1959 | PRODUCTOS INNOVADORES PROALMEX CIA. LTDA. | US$ 3.461.651 | US$ 203.411 | 57 | Azuay |
| 1960 | SERVICIOS Y PRODUCTOS DE INGENIERIA SERPRODIN S.A. | US$ 4.163.671 | US$ 304.693 | 4 | Guayas |
| 1961 | CONSORCIO PUENTE DAULE - GUAYAQUIL II | US$ 1.659.237 | US$ -838.682 | 3 | Guayas |
| 1962 | MODEIBERICA CIA. LTDA. | US$ 3.276.038 | US$ 221.352 | 31 | Pichincha |
| 1963 | SALESLAND ECUADOR S.A.S. | US$ 4.951.620 | US$ 68.816 | 225 | Pichincha |
| 1964 | BANLOPLAR CIA. LTDA. | US$ 1.818.672 | US$ 80.722 | 48 | El Oro |
| 1965 | PGS ECUADOR S.A. | US$ 2.137.976 | US$ 250.985 | 349 | Los Rios |
| 1966 | ACSUIN S.A. ACABADOS Y SUMINISTROS INDUSTRIALES | US$ 3.045.400 | US$ 111.491 | 32 | Pichincha |
| 1967 | SABIJER'S S.A. | US$ 3.372.256 | US$ 348.318 | 55 | Pichincha |
| 1968 | CEOLAKABADOS CIA.LTDA. | US$ 3.443.388 | US$ 31.928 | 27 | Pichincha |
| 1969 | FLORICOLA ATTAROSES CIA. LTDA. | US$ 3.543.856 | US$ 34.678 | 94 | Pichincha |
| 1970 | FLAMMO FLAMENCO MOTELES CIA. LTDA. | US$ 1.256.354 | US$ 22.424 | 40 | Pichincha |
| 1971 | SISMEING SISTEMAS MECANICOS E INGENIERIA S.A. | US$ 3.141.016 | US$ 48.834 | 57 | Guayas |
| 1972 | TRAVELSTORES S.A. | US$ 4.892.977 | US$ 132.494 | 73 | Pichincha |
| 1973 | IMPORTADORA PARTKOREA IMPORTADORA MUNDO KOREA S.A. | US$ 3.265.664 | US$ 74.538 | 8 | Guayas |
| 1974 | AGRILATEXA S.A. | US$ 3.009.279 | US$ 145.064 | 35 | Santo Domingo De Los Tsachilas |
| 1975 | DISETEC COMPAÑIA LIMITADA | US$ 2.438.551 | US$ -338.023 | 140 | Pichincha |
| 1976 | CONSORCIO INTERANDINO, INTERCONSORCIO S.A. | US$ 4.432.854 | US$ 50.604 | 31 | Guayas |
| 1977 | BRIKO S.A. | US$ 3.222.485 | US$ 113.870 | 3 | Guayas |
| 1978 | ECUAFOXSA S.A. | US$ 3.607.455 | US$ 38.657 | 33 | Guayas |
| 1979 | FAPLACA S.A. | US$ 3.695.719 | US$ 63.795 | 8 | Guayas |
| 1980 | CIRKWITOS S.A. | US$ 3.464.794 | US$ -1.679.504 | 62 | Pichincha |
| 1981 | CALIZAS Y MINERALES CALMOSACORP CIA.LTDA. | US$ 3.160.608 | US$ 116.026 | 42 | Guayas |
| 1982 | PFC ACCESOS AUTOMATICOS DEL ECUADOR S.A. | US$ 3.866.103 | US$ 152.916 | 21 | Pichincha |
| 1983 | CANEX AGRO S.A. | US$ 3.065.776 | US$ -245.156 | 34 | Guayas |
| 1984 | CABLEADOS PARA COMUNICACIONES CABLECOMSA S.A. | US$ 3.847.445 | US$ 41.070 | 25 | Pichincha |
| 1985 | DONUT HOUSE S.A. | US$ 4.974.257 | US$ -1.341.864 | 198 | Guayas |
| 1986 | DOBLONECUADOR S.A. | US$ 2.305.272 | US$ 55.114 | 19 | Azuay |
| 1987 | IC SERVICIOS DE SEGURIDAD PRIVADA DEL ECUADOR ICSSE CIA. LTDA | US$ 2.732.881 | US$ -217.586 | 183 | Pichincha |
| 1988 | ADVANCED TECHNOLOGIES S.A. VANDETSA | US$ 2.803.497 | US$ 42.257 | 25 | Guayas |
| 1989 | RALIUGA S.A. | US$ 2.299.422 | US$ 145.056 | 32 | Guayas |
| 1990 | PARAMOUNT PLANTAIN FARMS S.A.S. | US$ 1.103.908 | US$ 272.004 | 79 | Guayas |
| 1991 | MARKETING & TECHNOLOGY MARTEC CIA. LTDA | US$ 3.170.226 | US$ 4.772 | 4 | Pichincha |
| 1992 | IMPORTACIONES CASTRO CRESPO INTERNATIONAL COMPANY S.A. | US$ 4.983.963 | US$ 285.846 | 33 | Pichincha |
| 1993 | GALÁPAGOS MARINE EXPEDITIONS GALAMAREX CIA.LTDA. | US$ 2.162.276 | US$ 161.958 | 18 | Galapagos |
| 1994 | CARTOLAB CIA. LTDA. | US$ 4.071.181 | US$ 64.917 | 29 | Azuay |
| 1995 | INDUSTRIA DE CHANCHITOS INDUCHAN S.A. | US$ 2.797.299 | US$ 9.687 | 26 | Guayas |
| 1996 | JJINMO S.A. | US$ 1.002.911 | US$ 445.745 | 2 | Pichincha |
| 1997 | FABRICA PAPELERA BELLA PAPEL BELLAPAPEL S.A. | US$ 3.461.295 | US$ 130.428 | 15 | Guayas |
| 1998 | SOLUCIONES COMPUTACIONALES BITLOGIC S.A. | US$ 4.982.818 | US$ 110.866 | 12 | Pichincha |
| 1999 | MODASA S.A. | US$ 2.972.951 | US$ 74.964 | 3 | Azuay |
| 2000 | HORMI-CENTER CIA. LTDA. | US$ 3.663.552 | US$ 180.238 | 31 | Cañar |