| 1901 | IMELDA DE JARAMILLO CIA. LTDA. | US$ 19.506.265 | US$ 175.934 | 79 | Loja |
| 1902 | COMERCIALIZADORA DE COMBUSTIBLES CORPALUBRI S.A. | US$ 11.490.017 | US$ -265.286 | 17 | Guayas |
| 1903 | LATBIO S.A. | US$ 25.700.229 | US$ 302.406 | 7 | El Oro |
| 1904 | CIERPRONTI S.A. | US$ 18.083.623 | US$ 193.784 | 42 | Guayas |
| 1905 | ORIMEC, ORIENTAL MEDICAL DEL ECUADOR C.A. | US$ 8.674.233 | US$ -157.246 | 42 | Pichincha |
| 1906 | CAVIFACOM CIA. LTDA. | US$ 12.879.011 | US$ 342.670 | 27 | Azuay |
| 1907 | SOCIEDAD DE EXPORTACIONES E IMPORTACIONES MAPRIPLASTEC DEL ECUADOR S.A. | US$ 17.159.093 | US$ 591.180 | 24 | Guayas |
| 1908 | ILIANZA S.A. | US$ 13.109.604 | US$ 246.895 | 64 | Guayas |
| 1909 | FLORICULTURA JOSARFLOR S.A | US$ 10.544.049 | US$ 1.042.771 | 362 | Pichincha |
| 1910 | UNITY3-CORPORATION CIA.LTDA. | US$ 7.062.442 | US$ 5.704.545 | 2 | Pichincha |
| 1911 | PLUS SERVICES S.A. CORPSERVIPLUS | US$ 19.262.272 | US$ 1.305.446 | 1.133 | Guayas |
| 1912 | EXTRACTORA NATURAL ECUADOR S.A. EXTRANATU | US$ 15.191.655 | US$ -275.491 | 37 | Manabi |
| 1913 | SECURITY DATA SEGURIDAD EN DATOS Y FIRMA DIGITAL S.A. | US$ 14.085.775 | US$ 3.963.630 | 203 | Pichincha |
| 1914 | FABIANACORP S.A. | US$ 16.247.225 | US$ 2.184.367 | 86 | Guayas |
| 1915 | LABORATORIO-ACUATECSA ACUACULTURA & TECNOLOGIA S.A. | US$ 10.771.756 | US$ 156.669 | 2 | Santa Elena |
| 1916 | REFRESCOS SIN GAS S.A. RE.S.GA.SA | US$ 19.586.779 | US$ 33.660 | 660 | Guayas |
| 1917 | COMPANIA ANONIMA MORETRAN | US$ 15.000.643 | US$ 771.199 | 135 | Guayas |
| 1918 | AGRO SERVICIOS PVL CIA.LTDA. | US$ 12.812.231 | US$ 290.080 | 33 | Manabi |
| 1919 | COMPAÑIA CON ACEITES ECUADOR CONACEITES S.A. | US$ 22.502.209 | US$ 788.788 | 44 | Carchi |
| 1920 | ZAPIN S.A. | US$ 14.583.486 | US$ 198.261 | 264 | Guayas |
| 1921 | INDUSTRIA ARROCERA PORTILLA S.A. PORTIARROZ | US$ 13.318.762 | US$ 133.128 | 40 | Guayas |
| 1922 | AEME REPRESENTACIONES CIA.LTDA. | US$ 15.371.715 | US$ 45.680 | 27 | Pichincha |
| 1923 | ORIGINARSA S.A. | US$ 6.277.050 | US$ 1.177.785 | 49 | Pichincha |
| 1924 | COMERCIALIZADORA DIECAMGOLD CIA.LTDA. | US$ 24.563.021 | US$ 575.655 | 7 | Azuay |
| 1925 | ACRETI S.A. | US$ 12.910.364 | US$ 661.495 | 28 | Guayas |
| 1926 | INCORAZON S.A. | US$ 8.704.864 | US$ -27.247 | 25 | Pichincha |
| 1927 | EXPORTADORA DE FRUTAS EXPORTVAL S.A. | US$ 26.533.416 | US$ 51.397 | 18 | Guayas |
| 1928 | ROTDIUR S.A. | US$ 18.664.293 | US$ 39.104 | 75 | Guayas |
| 1929 | KELLOGG ECUADOR C. LTDA. ECUAKELLOGG | US$ 12.865.394 | US$ -5.367.864 | 25 | Guayas |
| 1930 | COMPAÑIA DE NEGOCIOS Y PROPIEDADES GRAN CONDOR CONPROGRA CIA.LTDA. | US$ 8.817.158 | US$ 870.509 | 207 | Pichincha |
| 1931 | BIOALAMOS S.A. | US$ 5.339.366 | US$ -289.218 | 69 | El Oro |
| 1932 | HIDROMECANICA ANDINA HIDROANDINA C LTDA | US$ 15.705.021 | US$ 552.806 | 37 | Guayas |
| 1933 | DIGICENTER S.A. | US$ 18.410.863 | US$ 145.425 | 59 | Guayas |
| 1934 | 1001CARROS-GBV S.A.S. | US$ 18.157.247 | US$ -796.391 | 60 | Guayas |
| 1935 | SCHRYVER DEL ECUADOR S.A. | US$ 19.053.328 | US$ 123.954 | 65 | Pichincha |
| 1936 | TRAMACOEXPRESS CIA. LTDA. | US$ 19.548.224 | US$ 248.571 | 519 | Pichincha |
| 1937 | CEMIX ECUADOR S.A.S. | US$ 8.660.747 | US$ 282.343 | 42 | Azuay |
| 1938 | UNNOMOTORS S.A. | US$ 17.099.092 | US$ 195.409 | 5 | Azuay |
| 1939 | INDUSTRIA ALUCAPS ECUADOR GA S.A. | US$ 7.492.965 | US$ 763.285 | 36 | Guayas |
| 1940 | TEXTILES INDUSTRIALES AMBATENOS S.A. TEIMSA | US$ 9.960.723 | US$ 607.273 | 139 | Tungurahua |
| 1941 | BESTFOODS-IMPORTS S.A. | US$ 24.088.705 | US$ 131.593 | 34 | Pichincha |
| 1942 | SVF ECUADOR S.A. | US$ 11.514.519 | US$ -49.384 | 57 | Guayas |
| 1943 | PRODISPRO PROVEEDORA Y DISTRIBUIDORA DE PRODUCTOS CIA. LTDA. | US$ 21.109.330 | US$ 106.882 | 145 | Imbabura |
| 1944 | DISTRIBUIDORA SUPRICE S.A. | US$ 27.025.896 | US$ 159.492 | 12 | Carchi |
| 1945 | UNICENTRO TURISTICO JABUCAM SA | US$ 5.782.641 | US$ -290.072 | 113 | Guayas |
| 1946 | NATURAL SEAFOOD NATUSEAFOOD C.LTDA. | US$ 17.792.525 | US$ 213.684 | 84 | Guayas |
| 1947 | VASERUM CIA.LTDA. | US$ 12.808.714 | US$ 501.712 | 349 | Pichincha |
| 1948 | ECUATORIANA DE NEGOCIOS ECUNE S.A. | US$ 12.403.987 | US$ -1.271.687 | 18 | Guayas |
| 1949 | GUEVARA VASCO CIA. LTDA. | US$ 15.460.312 | US$ 585.326 | 2 | Tungurahua |
| 1950 | DEPOSITO DENTAL NEO-TEC C LTDA | US$ 17.170.420 | US$ 1.162.199 | 21 | Guayas |
| 1951 | AVÍCOLA SANTA ELENITA SANTEEL CIA.LTDA. | US$ 16.265.894 | US$ 38.118 | 32 | Tungurahua |
| 1952 | ZAPEC S.A. | US$ 10.337.974 | US$ 111.610 | 256 | Guayas |
| 1953 | OCEANFISH S.A. | US$ 12.956.571 | US$ -101.536 | 95 | Manabi |
| 1954 | GARDAEXPORT S.A. | US$ 13.758.983 | US$ 1.644.949 | 534 | Pichincha |
| 1955 | UNNOCYCLES S.A. | US$ 19.161.630 | US$ 220.090 | 42 | Azuay |
| 1956 | MEGAKONS S.A. | US$ 17.886.406 | US$ 385.304 | 73 | Tungurahua |
| 1957 | FERROCENTER FERROCIMA S.A. | US$ 22.480.610 | US$ 253.899 | 114 | Guayas |
| 1958 | SUNAPA S.A. | US$ 12.612.011 | US$ 125.253 | 42 | Guayas |
| 1959 | TORVICMOSRA S.A. | US$ 9.679.859 | US$ 100.656 | 4 | Guayas |
| 1960 | IMPARCE S.A.S. | US$ 15.718.907 | US$ 111.761 | 4 | Guayas |
| 1961 | METALSUD S.A. | US$ 11.663.907 | US$ 2.594.577 | 69 | Pichincha |
| 1962 | VIBAG C.A. | US$ 10.978.383 | US$ 239.713 | 85 | Guayas |
| 1963 | PROCOPET PROYECTOS Y CONSTRUCCIONES PETROLERAS S.A. | US$ 9.881.309 | US$ 28.502 | 290 | Pichincha |
| 1964 | SANCECI CIA. LTDA. | US$ 17.949.752 | US$ 54.527 | 95 | Azuay |
| 1965 | JNG DEL ECUADOR S.A. | US$ 15.872.736 | US$ 723.982 | 3 | Guayas |
| 1966 | INDUSTRIA DE PRODUCTOS ALIMENTICIOS INPROLAC S.A. | US$ 17.542.176 | US$ 103.176 | 136 | Pichincha |
| 1967 | FIORENTINA FLOWERS S.A. | US$ 13.992.654 | US$ 1.150.666 | 486 | Pichincha |
| 1968 | EMIHANA CIA. LTDA. | US$ 11.796.307 | US$ 68.755 | 409 | Pichincha |
| 1969 | L'ORO DEL PACIFICO OROPAC S.A.S. | US$ 26.372.676 | US$ -11.199 | 2 | Guayas |
| 1970 | KRUGERCORPORATION S.A.S. | US$ 9.455.632 | US$ 59.633 | 163 | Pichincha |
| 1971 | ULTRANRG S.A.S. | US$ 27.135.393 | US$ 149.859 | 53 | Pichincha |
| 1972 | CONVERSA CONVERTIDORA DE PAPEL S.A. | US$ 12.427.002 | US$ 220.031 | 155 | Pichincha |
| 1973 | CERAMICAS AL COSTO S.A.S. | US$ 18.504.036 | US$ 395.594 | 102 | Santo Domingo De Los Tsachilas |
| 1974 | CHINA 15TH METALLURGICAL CONSTRUCTION GROUP CO., LTD. | US$ 17.616.033 | US$ 780.216 | 301 | Guayas |
| 1975 | DURACOLOR S.A. | US$ 9.950.259 | US$ 1.375.254 | 80 | Guayas |
| 1976 | PHARMACY & NUTRITION PHARNUTRI S.A. | US$ 6.780.400 | US$ 1.427.572 | 22 | Guayas |
| 1977 | SERVIREPUESTOS S.A. | US$ 15.057.997 | US$ 634.553 | 60 | Guayas |
| 1978 | INDUVALLAS CIA. LTDA. | US$ 12.034.867 | US$ 369.642 | 91 | Pichincha |
| 1979 | ZUKALO S.A. | US$ 14.691.492 | US$ 2.688.344 | 161 | Guayas |
| 1980 | CAMBRICA SELISA S.A. | US$ 6.666.301 | US$ 304.399 | 70 | Guayas |
| 1981 | TECNOTEMPE S.A. | US$ 12.162.253 | US$ 392.318 | 97 | Guayas |
| 1982 | SASEJUKI S.A.S. | US$ 13.551.917 | US$ -104.376 | 2 | Guayas |
| 1983 | LATINCOSMETIC S.A. | US$ 6.206.628 | US$ 1.101.928 | 4 | Guayas |
| 1984 | COMPAÑIA ECUATORIANA DE RECICLAJE CERSA S.A. | US$ 12.771.895 | US$ -634.279 | 69 | Pichincha |
| 1985 | IMPORTADORA DISJORELY CIA.LTDA. | US$ 20.876.674 | US$ 106.119 | 19 | Pichincha |
| 1986 | INDUSTRIALIZADORA Y COMERCIALIZADORA DE PALMITO S.A. INCOPALMITO | US$ 10.042.418 | US$ -990.905 | 145 | Esmeraldas |
| 1987 | INMOBILIARIA HABITAD YOREC INMOHABIYOREC S.A. | US$ 7.130.736 | US$ 279.480 | 19 | Pichincha |
| 1988 | PRODUCNORTE S.A. | US$ 5.393.887 | US$ -2.764.213 | 152 | Pichincha |
| 1989 | FGENTERPRISE S.A. | US$ 19.568.570 | US$ 686.500 | 8 | Santo Domingo De Los Tsachilas |
| 1990 | HOMETRADE S.A. | US$ 17.380.297 | US$ 518.804 | 27 | Manabi |
| 1991 | LICEO PANAMERICANO LPSA S.A. | US$ 12.634.399 | US$ 2.345.689 | 279 | Guayas |
| 1992 | RECURSOS TECNOLOGICOS ABIERTOS TECHRESOURCES CIA. LTDA. | US$ 15.450.873 | US$ 330.957 | 114 | Pichincha |
| 1993 | MAFRICO S.A. | US$ 12.207.458 | US$ 532.770 | 73 | Guayas |
| 1994 | PORKRIB S.A. | US$ 15.353.477 | US$ 2.048.430 | 95 | Santa Elena |
| 1995 | PANATWORLD LOGISTICS S.A. | US$ 12.475.076 | US$ 120.709 | 206 | Pichincha |
| 1996 | ECUANROS ECUADORIAN NEW ROSES SOCIEDAD ANONIMA | US$ 14.614.390 | US$ 862.292 | 455 | Pichincha |
| 1997 | AVES DEL ORIENTE S.A. ORIAVESA | US$ 12.273.819 | US$ 892.440 | 186 | Napo |
| 1998 | ANISHI S.A. | US$ 7.821.150 | US$ 653.121 | 125 | Guayas |
| 1999 | CAMBARU S. A. | US$ 6.500.932 | US$ 66.484 | 35 | Guayas |
| 2000 | PROAVICOLA CIA.LTDA. | US$ 20.215.435 | US$ 25.236 | 25 | Pichincha |