| 1901 | INDUSTRIAS LACTEAS SA INDULAC | US$ 15.935.259 | US$ 53.514 | 157 | Guayas |
| 1902 | SANTILLANA S.A. | US$ 17.511.791 | US$ 3.087.330 | 155 | Pichincha |
| 1903 | SOCIEDADES HOLDING S. A. SOCIEDADESHOLD | US$ 1.219.207 | US$ 522.216 | 2 | Guayas |
| 1904 | LANILLING S.A. | US$ 2.700.840 | US$ 2.577.038 | 2 | Guayas |
| 1905 | NEGOCIOS SOCIETARIOS SOCKEN C. LTDA. | US$ 384.329 | US$ 358.677 | 1 | Guayas |
| 1906 | CONVECTOR S.A. | US$ 18.097.264 | US$ 2.144.433 | 92 | Guayas |
| 1907 | TAPITEX M&B CIA. LTDA. | US$ 20.642.174 | US$ 228.792 | 66 | Azuay |
| 1908 | CONSTRUCTORA ALTAVISTACORP CIA.LTDA. | US$ 10.053.266 | US$ 670.076 | 54 | Azuay |
| 1909 | LABORATORIO FARMACEUTICO LAMOSAN C.L. | US$ 16.648.188 | US$ 85.088 | 189 | Pichincha |
| 1910 | PROINVESTING S.A.S. | US$ 32.304 | US$ 1.850.853 | 4 | Guayas |
| 1911 | NUTEC S.A. | US$ 17.276.039 | US$ -19.890 | 54 | Guayas |
| 1912 | INMOBILIARIA HELVETIA SA | US$ 2.097.019 | US$ 823.264 | 3 | Guayas |
| 1913 | ECUAFEED S.A. | US$ 21.170.788 | US$ 538.236 | 98 | Santa Elena |
| 1914 | CARNEGIE RIDGE RESOURCES S.A. | US$ 0 | US$ -110.649 | 2 | Pichincha |
| 1915 | ELELCOHOLD CIA.LTDA. | US$ 2.075.877 | US$ 1.833.815 | 12 | Azuay |
| 1916 | PETROCEANO S.A. | US$ 30.664.855 | US$ 159.577 | 19 | Manabi |
| 1917 | MOLLITIAM S.A. | US$ 6.428.027 | US$ -3.941.151 | 2 | Manabi |
| 1918 | ECUACYCLO CIA. LTDA. | US$ 12.754.057 | US$ 925.522 | 88 | Guayas |
| 1919 | CONSTRUCTORA DE DISEÑOS PRODUCTIVOS CONSTRUDIPRO S.A. | US$ 8.938.988 | US$ 8.673 | 416 | Guayas |
| 1920 | IMPORTADORA ORO AUTO IMOAUTO C. LTDA. | US$ 6.343.779 | US$ 67.289 | 13 | El Oro |
| 1921 | OPTICAS GMO ECUADOR S.A. | US$ 19.427.766 | US$ 931.963 | 262 | Guayas |
| 1922 | SANOFI-AVENTIS DEL ECUADOR S.A. | US$ 21.658.190 | US$ -11.271.467 | 7 | Pichincha |
| 1923 | ORCEVAL DISTRIBUCIONES CIA. LTDA. | US$ 1.712.753 | US$ -188.381 | 3 | Pichincha |
| 1924 | RECOR DENTAL Y QUIMEDIC CIA. LTDA. | US$ 10.744.746 | US$ 201.647 | 87 | Azuay |
| 1925 | VATIN ENTERPRISE-HOLDING S.A.S. | US$ 0 | US$ -745,8 | 2 | Pichincha |
| 1926 | ESVALHOLDING S.A. | US$ 6.190.862 | US$ 5.440.344 | 5 | Pichincha |
| 1927 | CLINICA INTERNACIONAL INTERSANITAS SA | US$ 13.347.743 | US$ -3.719.595 | 327 | Pichincha |
| 1928 | RODLAROK S.A. | US$ 15.147.549 | US$ 2.562.168 | 16 | El Oro |
| 1929 | AGROBERRUZ S.A. | US$ 16.152.683 | US$ 2.540.075 | 412 | Guayas |
| 1930 | TRANSPORTE Y COMERCIO INTERNACIONAL - TRANSCOMERINTER CIA. LTDA. | US$ 15.418.080 | US$ 155.517 | 136 | Pichincha |
| 1931 | ORTEGA'S COCOAFARM S.A. | US$ 32.032.541 | US$ 743.084 | 4 | Guayas |
| 1932 | CROPILETTO S.A. | US$ 27.963 | US$ -1.451.070 | 3 | Manabi |
| 1933 | PONCE DIAZ HOLDING PONCEHOLDING S.A. | US$ 12.737.186 | US$ 12.729.250 | 2 | Pichincha |
| 1934 | BIRA BIENES RAICES SA | US$ 9.991.916 | US$ 69.726 | 249 | El Oro |
| 1935 | SOTILEZA S.A. | US$ 8.855.394 | US$ -245.600 | 4 | Guayas |
| 1936 | EMPRESA LAFUENTE APART & SUITES LA&S S.A. | US$ 4.070.617 | US$ 194.221 | 242 | Pichincha |
| 1937 | FORTALTRIUN S.A. | US$ 2.798.375 | US$ 1.615.429 | 4 | Guayas |
| 1938 | AGROPLASTICOS CIA.LTDA. | US$ 16.334.483 | US$ -23.425 | 31 | Pichincha |
| 1939 | PETREX S.A. | US$ 10.474 | US$ 3.095 | 4 | Pichincha |
| 1940 | ARCHITEKTON S.A. | US$ 20.365.003 | US$ 314.402 | 13 | Guayas |
| 1941 | CAMPOSANTO JARDINES DEL EDEN S.A CAJARDENSA | US$ 3.687.719 | US$ -39.754 | 140 | Manabi |
| 1942 | RECORCHOLIS SA | US$ 15.608.285 | US$ 1.257.827 | 74 | Guayas |
| 1943 | ALITECNO COMERCIO DE INSUMOS PARA LA INDUSTRIA DE ALIMENTOS S.A. | US$ 20.781.292 | US$ 2.692.780 | 49 | Pichincha |
| 1944 | EXORBAN S.A. | US$ 29.206.095 | US$ -590.099 | 8 | El Oro |
| 1945 | SERVICIOS DE SEGURIDAD ARMILED CIA. LTDA. | US$ 12.509.963 | US$ 1.513.272 | 49 | Pichincha |
| 1946 | AGROVANIC S.A. | US$ 18.107.891 | US$ 2.575.085 | 187 | Guayas |
| 1947 | PRINTOPAC S.A.S. | US$ 18.643.540 | US$ 2.026.390 | 84 | Pichincha |
| 1948 | SPARE PARTS INDUSTRIAL & AUTOMOTRIZ SPARE-INDAUTO S.A. | US$ 18.494.468 | US$ 472.010 | 2 | Guayas |
| 1949 | EXPORTADORES DEL PACIFICO EXPA S.A.S. | US$ 31.981.194 | US$ 61.336 | 222 | Guayas |
| 1950 | PROAUDIO ANDRADE DURAN C.A. | US$ 13.443.907 | US$ 385.054 | 95 | Pichincha |
| 1951 | ABAD MENDIETA CIA. LTDA. | US$ 23.396.202 | US$ 45.349 | 164 | Cañar |
| 1952 | INDUBUSINESS S.A.S. | US$ 1.229.402 | US$ 247.659 | 2 | Azuay |
| 1953 | SAFIMO S.A. | US$ 3.255.366 | US$ 1.382.866 | 2 | Pichincha |
| 1954 | EMERGENT COLD ECUADOR S.A.S. | US$ 4.148.282 | US$ 671.467 | 47 | Guayas |
| 1955 | ALIMENTOS DEL GOLFO S.A.S. | US$ 21.445.896 | US$ 309.119 | 417 | Guayas |
| 1956 | FACTEC S.A. | US$ 2.976.696 | US$ -322.971 | 7 | Pichincha |
| 1957 | CEPEDA CIA. LTDA. | US$ 10.935.950 | US$ 590.597 | 95 | Tungurahua |
| 1958 | EMBOTELLADORA AZUAYA SA EASA | US$ 5.147.058 | US$ 966.029 | 53 | Azuay |
| 1959 | PACIFICOZONE S.A. | US$ 21.320.968 | US$ 384.321 | 20 | Guayas |
| 1960 | EXPORTADORA ALKATIFF AGRO LOPEZ CIA.LTDA. | US$ 31.436.574 | US$ 502.676 | 6 | Esmeraldas |
| 1961 | ECUABARNICES S.A. | US$ 17.045.756 | US$ 235.796 | 43 | Guayas |
| 1962 | PF GROUP S.A. | US$ 9.691.889 | US$ -246.887 | 81 | Pichincha |
| 1963 | INMOBILIARIA INTELCA C LTDA | US$ 12.898.464 | US$ 193.349 | 1.244 | Guayas |
| 1964 | USAFISH S.A. | US$ 18.281.770 | US$ 259.561 | 36 | Manabi |
| 1965 | MEGAFRIO S.A. | US$ 17.062.198 | US$ 416.849 | 94 | Pichincha |
| 1966 | DELIFRUIT S.A. | US$ 19.155.840 | US$ 378.451 | 359 | Guayas |
| 1967 | BANAFRUITCORP S.A. | US$ 1.614.059 | US$ -614.233 | 52 | Guayas |
| 1968 | DOSMILCORP S.A. | US$ 1.742.755 | US$ 673.688 | 4 | Guayas |
| 1969 | VICTORIA S.A. | US$ 0 | US$ 1.886.889 | 2 | Guayas |
| 1970 | LABORATORIOS HG C.A. | US$ 7.565.231 | US$ -805.897 | 212 | Guayas |
| 1971 | PREDIAL CAPITAN NAJERA S.A. | US$ 565.070 | US$ 570.883 | 2 | Guayas |
| 1972 | BRODMEN S.A. | US$ 17.390.258 | US$ 289.296 | 135 | Guayas |
| 1973 | SERSUPPORT CIA. LTDA. | US$ 22.861.393 | US$ 364.930 | 907 | Pichincha |
| 1974 | CIUDAD NOBOA ANP S.A. | US$ 120.835 | US$ 337,2 | 8 | Guayas |
| 1975 | PLASTIVILL S.A. | US$ 21.013.899 | US$ 992.973 | 202 | Guayas |
| 1976 | WAEL ALAM ETIQUETAS INTERNACIONALES CIA. LTDA. | US$ 11.837.592 | US$ 111.309 | 142 | Pichincha |
| 1977 | DELIBANANA S. A. | US$ 9.214.204 | US$ 1.916.647 | 136 | El Oro |
| 1978 | DIMUNE S.A. | US$ 20.201.361 | US$ 1.315.590 | 36 | Pichincha |
| 1979 | AGROPROMOTORA DEL COTOPAXI AGROCOEX S. A. | US$ 18.512.648 | US$ 292.970 | 299 | Cotopaxi |
| 1980 | SULTANA DEL CONDOR MINERA S.A. SULCOMI | US$ 14.426.242 | US$ 4.166.987 | 94 | Zamora Chinchipe |
| 1981 | ESTRUCTURAS DE ACERO ESACERO S.A. | US$ 13.069.704 | US$ 757.751 | 137 | Pichincha |
| 1982 | MONTANGELLO-INVESTMENTS S.A.S. | US$ 491.971 | US$ 19.644 | 1 | Pichincha |
| 1983 | SUPERMAQUINAS C.A. | US$ 14.700.452 | US$ 512.331 | 27 | Pichincha |
| 1984 | SURMOTOR S.A. | US$ 27.424.804 | US$ 230.721 | 76 | Pichincha |
| 1985 | ZAFRABLESSING HOLDING S.A.S. | US$ 9.010.190 | US$ 9.008.912 | 2 | Tungurahua |
| 1986 | ISOLATOT S.A. | US$ 21.459.314 | US$ 2.481.865 | 125 | Guayas |
| 1987 | COMGROPSA COMERCIALIZADORA AGROPECUARIA S.A. | US$ 862.349 | US$ 33.245 | 12 | El Oro |
| 1988 | PROMINE CIA. LTDA. | US$ 17.180.454 | US$ 1.539.817 | 396 | El Oro |
| 1989 | JARA SEGURIDAD JARASEG CIA. LTDA. | US$ 21.844.636 | US$ 227.720 | 1.408 | Orellana |
| 1990 | PAPELERA DEL PACÍFICO PADELPA CIA.LTDA. | US$ 1.571.413 | US$ 922.751 | 1 | Guayas |
| 1991 | BALANCEADOS NOVA S.A. BALNOVA | US$ 27.156.695 | US$ -23.711.993 | 18 | Guayas |
| 1992 | ASIACAR S.A. | US$ 21.630.977 | US$ -1.763 | 61 | Pichincha |
| 1993 | PACFISH S.A. | US$ 21.871.538 | US$ 54.826 | 5 | Guayas |
| 1994 | GOLDKING MINING COMPANY S.A. | US$ 6.235.194 | US$ -521,5 | 57 | El Oro |
| 1995 | GALAPAGOS ORGANIC ''ORGAL'' S.A. | US$ 1.642 | US$ 0 | 9 | Galapagos |
| 1996 | TADEC TECNICOS AGROPECUARIOS DEL ECUADOR C LTDA | US$ 18.832.881 | US$ 517.573 | 55 | Tungurahua |
| 1997 | MOVILCELISTIC DEL ECUADOR S.A. | US$ 21.594.110 | US$ 799.890 | 135 | Pichincha |
| 1998 | DOLMEN SA | US$ 4.347.705 | US$ 89.790 | 61 | Guayas |
| 1999 | PARTESCAT CIA.LTDA. | US$ 16.901.077 | US$ 730.246 | 132 | Pichincha |
| 2000 | EKIPPO HOLDING S.A.S. | US$ 2.748.030 | US$ 2.240.581 | 4 | Pichincha |